The pair's wedding album also features in the upcoming issue of US-based People magazine as part of an international deal.
This is the second marriage for Pitt, who wed Jennifer Aniston in 2000. They divorced in 2005.
Jolie was previously married to British actor Jonny Lee Miller for three years in the late 90s and to Billy Bob Thornton for three years before divorcing in 2003.
Both Jolie and Pitt are working on movies. Jolie’s second directorial effort, the Second World War odyssey Unbroken, will be released in December in the US.
Pitt stars in Fury, also a Second World War drama and due out in the US on October 17.